Abstract: The present work aims to investigate the removal of dye Rhodamine-B (RB) and Congo red (CR) dye from aqueous solutions by low cost bio-waste adsorbents, such as Maranta arundinacea activated carbon (MAC) under various experimental conditions. The effect of dye concentrations, contact time, temperature and adsorbent dose on the removal of dyes was studied. The kinetic experimental data were fitted to pseudo-first- and pseudo-second – order model. Results imply that adsorption of RB and CR on these adsorbents nicely followed the second order kinetics model and maximum adsorption capacity was found to be 88.4 mg/g for RB and 79.3 mg/g for CR, however it increase with increase in temperature for both dyes. Equilibrium adsorption was investigated by the Langmuir, Freundlich, Temkin, D-R and Jovanoic isotherms. The thermodynamics parameters of adsorption systems indicated spontaneous and exothermic process.
Key words: Activated carbon, Congo red, Isotherms, Kinetics, Rhodamine-B
[1]. A.S Alzaydien, Adsorption of methylene blue from aqueous solution onto a Low-cost Natural Jordanian Tripoli, Am.J. of Environ. Sci. 5, 2009, 197-208.
[2]. B. Noroozi, G.A. Sorial, H. Bahrami, M. Arami, Equilibriums and kinetic adsorption study of cationic dye by a natural adsorbent-silkworm pupa, J.Hazard.Mater B, 139, 2007, 167- 174.
[3]. M.A.M. Salleh, D.K. Mahmoud, W.A.W.A. Karim, A. Idris, Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review, Desalination, 280, 2011, 1-13.
[4]. S. Dawood, T.K. Sen, Removal of anionic dye Congo red from aqueous solution by raw pine and acid-treated pine cone powder as adsorbent: Equilibrium, thermodynamic, kinetics mechanism and process design, Water Res. 46, 2012, 1933-1946.
[5]. S. Chatterjee, B.P. Chatterjee, A.K. Guha, Adsorptive removal of Congo red, a carcinogenic textile dye by chitosan, hydrobeads: Binding mechanism, equilibrium and kinetics, Colloid Surf A: Physiochem. 299, 2007, 146-152.
[6]. S.Arivoli, M. Thenkuzhali, Adsorption of Rhodamine B by acid activated carbon- kinetic, thermodynamic and equilibrium'', Orbital, 2, 2009, 138-155,
[7]. M.N. Abbasi, R. Asl, Sonochemical degradation of Basic Blue 41 dye assisted by nanoTiO2 and H2O2, J. Hazard. Mater. 153, 2008, 942-947.
[8]. V.K. Gupta, A. Mittal, R. Jain, M. Mathur, S. Sikarwar, Photochemical degradation of hazardous dye- Safaranin-T using TiO2 catalyst, J. Colloid. Interface Sci. 309, 2007, 460-465.
[9]. L. Fan, Y. Zhou, W. Yang, G. Chen, F. Yang, Electrochemical degradation of aqueous solution of Amaranth azo dye on ACF under potentiostatic model, Dyes Pigments, 76, 2008, 440-446.
[10]. M.H. Zonoozi, M.R.A. Moghaddam, M. Arami, Coagulation/Flocculation of dye containing solutions using Polyaluminium chloride and alum, Water Sci. Technol. 59, 2009, 1343-1351.