Abstract: In this research we have attempted to develop a paper strip based chromatography technique for the on-site detection of heavy metals. Various heavy metal ions such as Pb 2+, Hg2+, Cd2+, Zn2+,, Fe3+, Mn2+ and Co2+ were chromatographed on paper strips impregnated with sodium diethyl- dithiocarbamate ( NADDC) and its admixture with Na2CO3, NaCl, CaNO3, NH4Cl, EDTA, H3PO4, CaCO3,Na2HPO4, H3PO4 and NaOH. Common solvents viz. acetone, acetonitrile, carbon tetrachloride, benzene, and isopropyl alcohol, aqueous NADDC and distilled water were employed as mobile phases. Semi quantitative and qualitative determination of selected heavy metals by visual comparison of colour intensities on the TLC plates as well as by measurement of of developed spot area has been experimentally accomplished. Appropriate onsite paper strip sensors have been developed for binary and multiple separations of selected heavy metals for different industrial wastewater.
Keywords: Industrial Waste Water, Metal Ion Chromatography, Sodium diethyldithiocarbamate
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